PREPARATION OF ANTIREFLECTIVE SILICA COATING BY THE SOL-GEL METHOD FOR HELIOTHERMIC POWER PLANTS
DOI:
https://doi.org/10.59627/cbens.2016.1914Keywords:
Antireflective coating, Sol-gel, Heliotermic Power PlantsAbstract
This work deals with the deposition of a thin layer of porous silica antireflective coating onto glass substrates. The films were deposited at different speeds and heat-treated at 425 °C for 30 minutes. The effects of heat treatment and film deposition rate on the films’ reflectance were evaluated. The diffuse reflectance was measured using ultraviolet-visible (UV-Vis) spectroscopy. Scanning electron microscopy (SEM) was used for microstructural evaluation of the films. The water contact angle upon the films surface was evaluated using a tensiometer and was based on the sessile drop technique. The mechanical characteristics of the films are evaluated by tape test and pencil hardness. The obtained sol-gel silica coatings were homogeneous and free of cracks. UV-Vis analysis of the glass substrate revealed a reflectance value of 3,86%, whereas the lowest reflectance value obtained for antireflective coatings was 2,72%. The contact angle measurement showed that, for all films, there was wetting of the film by water, characterizing them as hydrophilic. The adhesion of the films were 4B and the pencil hardness were3H.
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References
Airoldi, C., Farias, R. F., 2004, Alcóxidos como precursores na síntese de novos materiais através do processo sol-gel, Química Nova, v. 27, n. 1, p. 84-88.
American Society for Testing and Materials, 2010, ASTM D3359-09: Standard Test Methods for Measuring Adhesion by Tape Test. Estados Unidos.
American Society for Testing and Materials, 2011, ASTM D3363-05: Standard Test Method for Film Hardness by Pencil Test. Estados Unidos.
American Society for Testing and Materials, 2012, ASTM G173-03, Standard Tables for Reference Solar Spectral Irradiances: Direct Normal and Hemispherical on 37° Tilted Surface, Estados Unidos.
American Society for Testing and Materials, 2013, ASTM D7334-08: Standard Practice for Surface Wettability of Coatings, Substrates and Pigments by Advancing Contact Angle Measurement. Estados Unidos.
Bautista, M.C., Morales, A., 2003, Silica antireflective films on glass produced by the sol–gel method, Solar Energy Materials & Solar Cells, v. 80, p. 217-225.
Brinker, C. J., Scherer, G. W., 1990, Sol-Gel science: The physics and chemestry of sol-gel processing, Academic Press.
Burkarter, E., 2010, Desenvolvimento de Superfícies Superhidrofóbicas de Politetrafluoretileno, Tese de Doutorado em Física, Universidade Federal do Paraná, Curitiba.
Karasiński, P., 2006, Influence of aging and annealing on the properties of silica films produced with sol-gel method, Optica Applicata, v. 36, n. 2-3, p. 389-399.
Kesmez, Ö., Çamurlu, H. E., Burunkaya, E., Arpaç, E., 2010, Preparation of antireflective SiO2 nanometric films, Ceramics International, v. 36. p. 391-394.
Kesmez, Ö., Burunkaya , E., Kiraz, N., Çamurlu, H. E., Asiltür, M., Arpaç, E., 2011, Effect of acid, water and alcohol ratios on sol-gel preparation of antireflective amorphous SiO2 coatings, Journal of Non-Crystalline Solids, v. 357, p. 3130-3135.
Nassar, E. J., Messaddeq, Y., Ribeiro, S. J. L., 2002, Influência da catálise ácida e básica na preparação da sílica funcionalizada pelo método sol-gel, Química Nova, v. 25, n. 1, p. 27-31.
Nunes, B. M. F., 2008. Funcionalização de superfícies de silício por radiação laser e implantação iónica: Estudo da molhabilidade, Dissertação de Mestrado em Engenharia de Materiais, Universidade Técnica de Lisboa, Lisboa, Portugal.
San Vicente, G., Bayón, R., Germán, N., Morales, A., 2011, Surface modification of porous antireflective coatings for solar glass covers, Solar Energy, v. 85. p. 676-680.
Xin, C.; Peng, C.; Xu, Y.; Wu, J., 2013, A novel route to prepare weather resistant, durable antireflective films for solar glass. Solar Energy, v. 93. p. 121-126.
Ye, H., Zhang, X., Zhang, Y., Ye, L., Xiao, B. LV, H., Jiang, B., 2011, Preparation of antireflective coatings with high transmittance and enhanced abrasion-resistance by a base/acid two-step catalyzed sol–gel process, Solar Energy Materials & Solar Cells, v. 95. p. 2347-2351.